研究者情報 | 神奈川大学

キハラ　ノブヒロ Kihara Nobuhiro 木原　伸浩所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
言語種別	英語
発行・発表の年月	2003/05
形態種別	学術雑誌
査読	査読あり
標題	Synthesis, Properties and Reaction of Polysulfilimine
執筆形態	共著
掲載誌名	J. Polym. Sci., Part A: Polym. Chem.
巻・号・頁	41(9),pp.1330-1334
著者・共著者	Sumiko Matsumura, Nobuhiro Kihara, and Toshikazu Takata
概要	The prepn. of a well-characterized main-chain-type polysulfilimine is reported. The starting arom. polysulfide Ar-CO-C6H4-S-C6H4-S-C6H4-S-C6H4-CO-Ar (all-4,4'-substitution, Ar = 5-(4-chlorobenzoyl)-2,6-dimethyl-1-naphthyl) was reacted with chloramine-T in CHCl3/H2O system under phase-transfer conditions (Bu4NCl) yielding poly(N-tosylsulfilimine) that was detosylated to the desired polysulfilimine Ar-CO-C6H4-S-C6H4-S(=NH)-C6H4-S-C6H4-CO-Ar. Effects of conversion of sulfide groups into sulfilimine groups on polymer properties (in particular, glass transition temp.) are discussed.
DOI	10.1002/pola.10661
ISSN	0887-624X