研究者情報 | 神奈川大学

ホリ　ヒサオ Hori Hisao 堀　久男所属神奈川大学理学部理学科神奈川大学大学院理学研究科理学専攻（化学領域）職種教授
発表年月日	2024/09/30
発表テーマ	Permanganate-Induced Complete Mineralization of Lithium Bis(pentafluoroethanesulfonyl)imide and Related Electrolyte Fluorochemicals in Superheated Water
発表学会名	44th International Symposium on Halogenated Persistent Organic Pollutants (POPs) (DIOXIN 2024)
主催者	National University of Singapore
学会区分	国際学会
発表形式	口頭（一般）
単独共同区分	単独
国名	シンガポール
開催地名	Singapore
開催期間	2024/09/29～2024/10/04
発表者・共同発表者	Hisao Hori, Keisuke Okamura, Kaito Suzuki, Michael Biermann
概要	Since the late 1990s, lithium bis(pentafluoroethanesulfonyl)imide, Li[N(SO2C2F5)2], has been widely studied as an electrolyte component for use in rechargeable lithium-ion batteries, lithium batteries, lithium−air batteries and all-solid-state lithium batteries. While Li[N(SO2C2F5)2] contributes to the safety of such batteries, it falls into the category of per- and polyfluoroalkyl substances (PFASs). Under these circumstances, waste-treatment technologies that afford complete decomposition of Li[N(SO2C2F5)2] and its analogues are needed. Herein we examined the mineralization of Li[N(SO2C2F5)2] in superheated water. We also applied our approach to two potassium salt analogues, one bearing [N(SO2C4F9)2]- and one bearing cyclic [N(SO2CF2)2CF2]-, which are also used as electrolytes and other applications.