ホリ ヒサオ   Hori Hisao
  堀 久男
   所属   神奈川大学  理学部 理学科
    神奈川大学大学院  理学研究科 理学専攻(化学領域)
   職種   教授
発表年月日 2022/08/16
発表テーマ Complete mineralization of fluorinated ionic liquids using low-temperature superheated water
発表学会名 20th European Symposium on Fluorine Chemistry
主催者 Humboldt Universitat zu Berlin
学会区分 国際学会
発表形式 口頭(一般)
単独共同区分 単独
開催地名 Berlin
発表者・共同発表者 Hisao Hori, Satomi Oishi
概要 Ionic liquids (ILs) are cutting-edge materials for green chemistry applications because they have unique characteristics such as negligible vapor pressure, high thermal and chemical stability, and high solvation ability, and they are non-flammable. Among them, fluorinated ILs (F-ILs) are used as electrolytic media for energy-related applications in supercapacitors, batteries, solar cells, and actuators, because they not only have the common characteristics of ILs but they also fulfill crucial requirements for electrochemical devices. The increasing number of usages of F-ILs has led to increased examination of their aquatic toxicity. We report herein an effective method that allows complete mineralization of two F-Ils in superheated water at a relatively low temperature (300 °C) by using KMnO4 as an oxidizing agent.