ホリ ヒサオ   Hori Hisao
  堀 久男
   所属   神奈川大学  理学部 化学科
   職種   教授
発表年月日 2019/05/24
発表テーマ Permanganate-induced efficient mineralization of fluorinated ionic liquids in subcritical water
発表学会名 International Conference on Fluorine Chemistry 2019
主催者 The 155th Committee on Fluorine Chemistry, JSPS
学会区分 国際学会
発表形式 ポスター
単独共同区分 単独
開催地名 Himeji
発表者・共同発表者 Satomi Oishi, Hiroki Kato, Ryota Kodama, Hisao Hori
概要 Ionic liquids (ILs) have been investigated for green chemistry applications such as solvents and co-catalysts. Furthermore, there has been increasing interest in their electrochemical applications, mainly as electrolytes that are safer than organic solvents. In particular, fluorinated ILs are introduced in many electrochemical devices.Herein an effective method for complete decomposition of room-temperature ILs, [Me3PrN][(CF3SO2)2N] and [C3mpip][(CF3SO2)2N] (C3mpip = 1-methyl-1-propylpiperidium ion), in subcritical water at lower temperature (~300 ºC) in the presence of KMnO4 is presented.