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カベ ヨシオ
Kabe Yoshio 加部 義夫 所属 神奈川大学 理学部 理学科 神奈川大学大学院 理学研究科 理学専攻（化学領域） 職種 教授 |
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| 発表年月日 | 2015/12/15 |
| 発表テーマ | Synthesis of Sila-bicycles by Ring-Clothing Diene-yne Metathesis Reaction ORG-1047 |
| 発表学会名 | The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem) |
| 主催者 | The Chemical Society of Japan |
| 学会区分 | 国際学会 |
| 発表形式 | ポスター |
| 単独共同区分 | 共同 |
| 開催地名 | Honolulu Hawaii |
| 発表者・共同発表者 | Yoshinori Nakamura, Junya Yasumatsu, Yoshio Kabe |
| 概要 | Ru-catalyzed selective dieneyne methathesis of dienyl ethynyl silane were carried out, in which the structure of the bicyclic product was chemically correlated with the corresponding hydrogenated product.The theoretical calculation favor ene-first route rather than yne-first routes energy difference was found in the before but was not in the latter.
Finally the isolated intermediate may be leading the final bicycle silicon product. |
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