カベ ヨシオ   Kabe Yoshio
  加部 義夫
   所属   神奈川大学  理学部 化学科
    神奈川大学大学院  理学研究科 理学専攻(化学領域)
   職種   教授
発表年月日 2015/12/15
発表テーマ Synthesis of Sila-bicycles by Ring-Clothing Diene-yne Metathesis Reaction ORG-1047
発表学会名 The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
主催者 The Chemical Society of Japan
学会区分 国際学会
発表形式 ポスター
単独共同区分 共同
開催地名 Honolulu Hawaii
発表者・共同発表者 Yoshinori Nakamura, Junya Yasumatsu, Yoshio Kabe
概要 Ru-catalyzed selective dieneyne methathesis of dienyl ethynyl silane were carried out, in which the structure of the bicyclic product was chemically correlated with the corresponding hydrogenated product.The theoretical calculation favor ene-first route rather than yne-first routes energy difference was found in the before but was not in the latter.
Finally the isolated intermediate may be leading the final bicycle silicon product.