研究者情報 - 廣津　昌和

（最終更新日：2022-12-09 16:58:36）

  ヒロツ　マサカズ   Hirotsu Masakazu
  廣津　昌和
   所属   神奈川大学理学部化学科

神奈川大学大学院理学研究科理学専攻（化学領域）

職種教授

■ 専門分野

無機化学, 錯体化学, 有機金属化学

■ 学位等

博士（理学）

■ 著書・論文歴

1.	論文	Crystal structures and electrochemical properties of nickel(II) complexes with N,N',N'',S-tetradentate Schiff base ligands （共著） 2022
2.	論文	Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands （共著） 2021
3.	論文	Iron Carbonyl Complexes Containing N,C,S-Tridentate Ligands with Quinoline, Vinyl, and Benzenethiolate Units （共著） 2020
4.	論文	芳香族置換基を導入したN,C,S-ピンサー鉄錯体の合成と分光学的性質（共著） 2020/10
5.	論文	Tetra- and dinuclear manganese complexes of xanthene-bridged O,N,O-Schiff bases with 3-hydroxypropyl or 2-hydroxybenzyl groups: ligand substitution at a triply bridging site （共著） 2019
6.	論文	CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands （共著） 2018
7.	論文	近赤外光応答性一酸化炭素放出物質の開発─ガス医療への応用を目指して─ （共著） 2018/08
8.	論文	Iron carbonyl complexes of N,C,S-pincer ligands with a pendant thioether arm: Synthesis, structures and reactivity （共著） 2018
9.	論文	Carbon-Sulfur Bond Cleavage Reactions of Quinolyl-Substituted Thiophenes with Iron Carbonyls （共著） 2017
10.	論文	Visible-light-induced release of CO by thiolate iron(III) carbonyl complexes bearing N,C,S-pincer ligands （共著） 2016
11.	論文	Fluorescence behaviour of an anthracene-BODIPY system affected by spin states of a dioxolene-cobalt centre （共著） 2016
12.	論文	Formation, reactivity and redox properties of carbon- and sulfur-bridged diiron complexes derived from dibenzothienyl Schiff bases: effect of N,N- and N,P-chelating moieties （共著） 2015
13.	論文	Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C-S Bond Cleavage and CO Insertion （共著） 2015
14.	論文	Di- and Mononuclear Iron Complexes of N,C,S-Tridentate Ligands Containing an Aminopyridyl Group: Effect of the Pendant Amine Site on Catalytic Properties for Proton Reduction （共著） 2015
15.	論文	Redox Properties and Catalytic Ability toward Electrochemical Proton Reduction of Sulfur Bridged Trinuclear Mo₃S₄ Complexes Containing Acetate, Trifluoroacetate, and/or Dithiophosphate as Bridging Ligands （共著） 2015
16.	論文	Diiron Carbonyl Complexes Bearing an N,C,S-Pincer Ligand: Reactivity toward Phosphines, Heterolytic Fe-Fe Cleavage, and Electrocatalytic Proton Reduction （共著） 2014
17.	論文	Synthesis, magnetic properties and dynamic behavior of cobalt complexes with an anthracene-containing dioxolene ligand （共著） 2014
18.	論文	Fine-Tuning the Energy Barrier for Metal-Mediated Dinitrogen N≡N Bond Cleavage （共著） 2014
19.	論文	Titanium and manganese complexes supported by a xanthene-bridged bis(tripodal N₂O₂) ligand: isomerization, intramolecular hydrogen bonding and metal-binding ability （共著） 2013
20.	論文	Skeletal Modification of Benzothiophene Mediated by Iron Carbonyls: Insertion of Terminal Alkynes with Migration of Amino and Alkoxy Groups （共著） 2013
21.	著書	化学演習シリーズ7　無機化学演習（共著） 2012/10
22.	論文	Carbon- and Sulfur-Bridged Diiron Carbonyl Complexes Containing N,C,S-Tridentate Ligands Derived from Functionalized Dibenzothiophenes: Mimics of the [FeFe]-Hydrogenase Active Site （共著） 2012
23.	論文	Anion-Controlled Assembly of Four Manganese Ions: Structural, Magnetic, and Electrochemical Properties of Tetramanganese Complexes Stabilized by Xanthene-Bridged Schiff Base Ligands （共著） 2012
24.	論文	Design, synthesis, magnetic properties of a π-radical ligand with photo-excited high-spin state and its Fe(II) complex. The first stage of a new strategy for LIESST materials. （共著） 2012
25.	論文	Bis(μ₂-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) （共著） 2012
26.	論文	Sulfur-Bridged Ta-M (M = Mo, Cr) Multinuclear Complexes Bearing a Four-Electron-Reduced Dinitrogen Ligand （共著） 2011
27.	論文	Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonyls （共著） 2011
28.	論文	(η⁶-Benzene){2-[2-(tert-butylsulfanyl)phenyl]pyridine-κ²N,S}chloridoruthenium(II) hexafluoridophosphate （共著） 2011
29.	論文	Preparation and Structural Features of Cu(I)Cu(II) Coordination Polymers Obtained by using Tripodal Complexes as Bridging Ligands （共著） 2011
30.	論文	Redox Controlled, Reversible Rearrangement of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an "N,S-confused" 2-Pyridylthiolate Arm （共著） 2011
31.	論文	Synthesis and characterization of xanthene-bridged Schiff base dimanganese(III) complexes: bimetallic catalysts for asymmetric oxidation of sulfides （共著） 2010
32.	論文	Manganese(II), Nickel(II), and Palladium(II) Complexes of a Terpyridine-Like Ligand Containing a Sulfur Linkage, and an Analogous NCN Pincer Palladium(II) Complex: Synthesis, Characterization, and Pd-Catalyzed Reactions （共著） 2010
33.	論文	Carbene-carbanion equilibrium for tris(2-pyridylthio)methanido Fe(II) complexes （共著） 2010
34.	論文	Steric, geometrical and solvent effects on redox potentials in salen-type copper(II) complexes （共著） 2009
35.	論文	Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C-S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes （共著） 2008
36.	論文	A Thiacalix[3]pyridine Copper(I) Complex as a Highly Active Catalyst for the Olefin Aziridination Reaction （共著） 2008
37.	論文	Reactions of a Gallium-Bridged Diiron Complex with Alkyl Lithium, HCl, and Phosphines （共著） 2008
38.	論文	Dinitrogen Activation at Ambient Temperatures: New Modes of H₂ and PhSiH₃ Additions for an "End-On-Bridged" [Ta(IV)]₂(μ-η¹:η¹-N₂) Complex and for the Bis(μ-nitrido) [Ta(V)(μ-N)]₂ Product Derived from Facile N-N Bond Cleavage （共著） 2007
39.	論文	Extreme N-N Bond Elongation and Facile N-Atom Functionalization Reactions within Two Structurally Versatile New Families of Group 4 Bimetallic "Side-on-Bridged" Dinitrogen Complexes for Zirconium and Hafnium （共著） 2007
40.	論文	Photochemical Reaction of CpFe(CO)₂SiMe₃ (Cp = η⁵-C₅H₅) with a Trihydrosilane Containing a Bulky Amino Substituent, Bis(trimethylsilyl)aminosilane （共著） 2007
41.	論文	Synthesis and Structure of a Dmpe-Substituted Dinuclear Complex Bridged by a Substituent-Free Gallium Atom: Electronic Effect of Metal Fragment on the Iron-Gallium Bonding （共著） 2007
42.	論文	Novel Aggregation of Bis(thiolato)-type Cobalt(III) Octahedra Assisted by Silver(I) Ions: Structural Interconversion by Counter Anions （共著） 2006
43.	論文	Sulfur-Bridged Dinuclear and Tetranuclear Complexes Consisting of cis-[Ru(bpy)₂]²⁺ and cis-[Ni(aet)₂] Units （共著） 2006
44.	論文	Synthesis and Reactivity of a Donor-Free (Silyl)(silylene)molybdenum Complex: Novel Insertion Reaction of an Isocyanide into a Si-C Bond （共著） 2006
45.	論文	A Remarkable Co^IIIMn^IIAg^I Heterometallic Aggregate with L-Cysteinate That Accommodates Chiral Cobalt(III) Octahedra in a 1D Channel （共著） 2005
46.	論文	A Two-Dimensional Clathrate Hydrate Sandwiched by Planar Arrays of a Copper Complex （共著） 2005
47.	論文	Alkylation of Nonbridging Thiolato Groups in an S-bridged Co^IIIPd^IICo^III Trinuclear Complex: Control of Geometrical Isomerism by Tuning Trans Influence Due to Sulfur Donors （共著） 2005
48.	論文	Sulfur-bridged Linkage of [Ni(thiolato)₂(amine)₂]-type Complexes with Linear Gold(I) Ions Assisted by Aurophilic Interaction （共著） 2005
49.	論文	Synthesis and Structures of the First Titanium(IV) Complexes with Cyclic Tetrasiloxide Ligands: Incomplete and Complete Cage Titanosiloxanes （共著） 2005
50.	論文	Synthesis of a Cofacial Schiff-Base Dimanganese(III) Complex for Asymmetric Catalytic Oxidation of Sulfides （共著） 2005
51.	論文	The First Ru^IIPd^II₂S₃ Metallochelate Ring Formed on a [Ru(bpy)₂]²⁺ Core （共著） 2005
52.	論文	An unexpected chelate conformation in trans-[(R)-N,N'-bis(α-phenyl salicylidene)propane-1,2-diaminato(2-)]bis(1-methyl-1H-imidazole-κN³)cobalt(III) perchlorate （共著） 2004
53.	論文	Novel Aggregation of [Ni(thiolato)₂(amine)₂] Type Square Planes Assisted by Silver(I) Ions （共著） 2004
54.	論文	Sulfur-Bridged Co^IIIPt^IICo^III Trinuclear Complexes with Mixed Aliphatic and Aromatic Thiolate Ligands: Effect of Non-Bridging Ligands on the Homochiral Linkage of Cobalt(III) Octahedrons by Platinum(II) （共著） 2004
55.	論文	Synthesis, characterization and stereochemistry of S-bridged Co^IIIMCo^III (M = Pd^II, Pt^II) trinuclear complexes containing two non-bridging thiolato groups: building blocks for the construction of chiral heterometallic aggregates （共著） 2004
56.	著書	キラキラわくわく化学（共著） 2003/07
57.	論文	A New Class of S-Bridged Co^IIIMCo^III (M = Ni^II, Pd^II) Trinuclear Complexes with Mixed Aliphatic and Aromatic Thiolate Ligands: Synthesis, Characterization, and Stereochemistry （共著） 2003
58.	論文	The First Triple Thiol-Thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers （共著） 2003
59.	論文	A Remarkable 14-Nuclear Re^V₈Ag^I₆ Coordination Oligomer Derived from a 2D (Re^V₂Ag^I₂)_n Coordination Polymer with D-Penicillaminate （共著） 2002
60.	論文	Aggregation of Cobalt(III) Complexes with Single Thiolato or Selenolato Group Assisted by Ag^I Ion: Crystal Structures of Spontaneously Resolved 1D Coordination Polymers [Ag{Co(aet or aese)(en)₂}](NO₃)₃ (aet = 2-Aminoethanethiolate, aese = 2-Aminoethaneselenolate) （共著） 2002
61.	論文	Antiferromagnetism Induced by Successive Protonation of Terminal Phenol Groups of a Bis(μ-phenoxide)-Bridged Dicopper(II,II) Complex （共著） 2002
62.	論文	First Aggregation of L-Cysteinato Cobalt(III) Octahedrons Assisted by Trigonal-Planar Silver(I) and Trigonal-Prismatic Sodium(I) Ions （共著） 2002
63.	論文	Linkage of [Cr(aet)₃] or [Cr(D-pen-N,O,S)₂]^- Octahedral Units by Forming S-Bridged Structures with AgI or AuI Ions (aet = 2-Aminoethanethiolate, D-pen = D-Penicillaminate) （共著） 2002
64.	論文	Rhodium(III) Complexes with Thiolate and Thioether Ligands Derived from fac(S)-[Rh(aet)₃] (aet = 2-Aminoethanethiolate): Selective Formation, Characterization and Properties （共著） 2002
65.	論文	Spontaneous Reduction of Gold(III) to Gold(I) That Leads to the Formation of S-Bridged Co^III₂Au^I₂ Tetranuclear Structure Composed of Unprecedented C1-cis(S)-[Co(aet)₂(en)]⁺ Units: Synthesis and Characterization of C₂C₂- and C₁C₁-[Au₂{Co(aet)₂(en)}₂]⁴⁺ （共著） 2002
66.	論文	Stereoselective Preparation and Crystal Structures of ΔΛ- and ΔΔ-[Hg{Co(aet)₂(en)}₂]⁴⁺ (aet = 2-Aminoethanethiolate): Conversion of a Racemic Co^IIIHg^II Dinuclear to an Optically Active Co^IIIHg^IICo^III Trinuclear Structure （共著） 2002
67.	論文	Sulfur-Bridged Co^IIIPt^IICo^III Trinuclear Complex Acting as an S-Donating Complex-Ligand （共著） 2002
68.	論文	Synthesis and Magnetic Properties of Mn^IIIMn^IIMn^III Trinuclear Complexes with Hydroxo Bridges. Comparison of Magnetic Properties between Hydroxo- and Alkoxo-Bridged Complexes by Density Functional Calculations （共著） 2002
69.	論文	Synthesis, Characterization, and Chiral Behavior of S-Bridged Co^IIIPt^IICo^III Trinuclear Complexes Composed of Bis(thiolato)-type Octahedral Units cis(S)-[Co(aet)₂(en)]⁺ and/or trans(N)-[Co(D-pen-N,O,S)₂]^- (aet = 2-Aminoethanethiolate, D-pen = D-Penicillaminate) （共著） 2002
70.	論文	(2-Aminoethanethiolato-N,S)bis(ethylenediamine-N,N')cobalt(III) Dinitrate （共著） 2001
71.	論文	Di- and Trinuclear Nickel(II) Complexes Containing Tripodal Hexadentate Ligands （共著） 2001
72.	論文	First Diastereomerically Controlled Aggregation of L-Cysteinato Cobalt(III) Octahedra, Assisted by Silver(I) Ions （共著） 2001
73.	論文	Synthesis, Characterization, and Stereochemistry of Oxorhenium(V) Complexes with 2-Aminoethanethiolate （共著） 2001
74.	論文	Enantioselective Aggregation of Cobalt(III) Octahedrons in a One-Dimensional S-Bridged Co^IIIAg^I Array That Leads to Spontaneous Resolution （共著） 2000
75.	論文	First Geometrical Isomerization of [Co(D-pen-N,O,S)₂]^- Induced by Forming S-Bridged Structure with Au^I or Ag^I: Crystal Structure of a Co^III₃Au^I₃ Hexanuclear Metallacycle [Au₃{Co(D-pen-N,O,S)₂}₃] (D-pen = D-Penicillaminate) （共著） 2000
76.	論文	Optical Resolution of a Six-Coordinate Silicon(IV) Complex with a Tripodal Hexadentate Ligand （共著） 2000
77.	論文	Preparation and Properties of Dinuclear Dioxomolybdenum(VI) Complexes with ONO-ONO-Type Hexadentate Schiff Base Ligands （共著） 2000
78.	論文	Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral Co^III, Square-Planar Pd^II, and Linear Au^I or Ag^I Ions （共著） 2000
79.	論文	Spontaneous Reduction of Gold(III) to Gold(I) by Forming Sulfur-Bridged Polynuclear Structure with Octahedral Tris(thiolato) Complexes （共著） 2000
80.	論文	Chiral-Selective Formation of S-Bridged Co^IIIPd^IICo^III Trinuclear Complexes by Using trans(N)-[Co(D-pen-N,O,S)₂]^- as a Bidentate-S,S Complexed Ligand (D-pen = D-Penicillaminate) （共著） 1999
81.	論文	Heteronuclear Fe^IIIMn^IIFe^III and Homonuclear Fe^IIIFe^IIIFe^III Complexes with a Tripodal Tetradentate Ligand （共著） 1999
82.	論文	A Complete Series of Stepwise Oxidation of [Co(2-pyridinethiolato)(en)₂]²⁺. Characterization of the 2-Pyridinesulfenato-N,S and -N,O, 2-Pyridinesulfinato-N,S and -N,O, and 2-Pyridinesulfonato-N,O Complexes （共著） 1998
83.	論文	Steric Control of Polynuclear Manganese Complexes by the Use of Tripodal Tetradentate Ligands （共著） 1998
84.	論文	Mononuclear and Mixed-Valence Trinuclear Manganese Complexes Containing Tripodal Tetradentate Ligands. Phenolato, Carboxylato, and Alkoxo Bridges （共著） 1997
85.	論文	Photochemistry of Cobalt(III) Complexes Containing a Sulfinate-S Ligand. Linkage and Geometrical Isomerization （共著） 1996
86.	論文	Stereochemistry and Electrochemistry of Cobalt(II) and Cobalt(III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands （共著） 1996
87.	論文	Synthesis, Characterization, and Molecular Mechanics Calculations of Optically Active Silatrane Derivatives （共著） 1996
88.	論文	Manganese(III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands. Effect of Phenyl Substituents （共著） 1995
89.	論文	Photochemical Reaction of (L-cysteinesulfinato-N,S){tris(2-aminoethyl)amine}cobalt(III). Formation of a Cobalt(III) Complex with an Uncoordinated Sulfinate Group （共著） 1994
90.	論文	Steric Control of Redox Potentials of Cobalt(II) Schiff Base Complexes with Phenyl Substituents （共著） 1994
5件表示
全件表示(90件)

■ 学会発表

1.	2022/03/24	ピリダジン部位を含むジベンゾチオフェン誘導体を用いたチオラート鉄錯体の合成（日本化学会第102春季年会）
2.	2021/09/16	キサンテン架橋チオラート配位子を持つ多核鉄錯体の合成と性質（第71回錯体化学会討論会）
3.	2020/03/20	Substituent Effect on Redox Behavior of N,C,S-Pincer Iron Carbonyl Complexes Bearing a Quinolyl Group（日本化学会第100春季年会）
4.	2019/09/23	硫黄および窒素ドナーを含むN-ヘテロ環状カルベン錯体の合成と性質（錯体化学会第69回討論会）
5.	2019/09/23	チオフェン誘導体を用いたメタラサイクル鉄錯体の合成と性質（錯体化学会第69回討論会）
6.	2019/03/16	Synthesis and Properties of N,C,S-Pincer Iron Carbonyl Complexes Bearing a Quinolyl Group（日本化学会第99春季年会）
7.	2018/12/07	Photoreactivity of Thiolate Iron Metallacyclic Complexes Derived from Functionalized Thiophenes（The 2nd International Symposium on Coordination Ionic Compounds）
8.	2018/08/02	Reactivity of iron carbonyl complexes of N,C,S-pincer ligands with a pendant thioether arm（43rd International Conference on Coordination Chemistry (ICCC2018)）
5件表示
全件表示(8件)

■ ホームページ

https://www.sci.kanagawa-u.ac.jp/chem/hirotsu/

■ 取得特許

2018/09/20

一酸化炭素放出分子（2018-145105）

■ 本学関連サイト

1.	「神大の先生」サイトページ