Information on researchers - Hikichi Shiro

(Last updated : 2024-07-12 17:24:26)

Hikichi Shiro
Kanagawa University Faculty of Chemistry and Biochemistry Department of Applied Chemistry

Kanagawa University Graduate School Graduate School of Engineering Course of Engineering (Field of Applied Chemistry)

Kanagawa University Graduate School Graduate School of Engineering Course of Engineering (Field of Bio and Life Engineering)

Professor

■ Present specialized field

Inorganic chemistry, Biomimetic chemistry, Catalytic chemistry (Key Word：Coordination chemistry, Cataltic chemistry, Bioinorganic chemistry, Organometallic chemistry)

■ Book and Papers

1.	Papers	Switching Product Selectivity in Immobilized Tungstate Catalysts by Control of Hydrophobicity of Mesoporous Silicate Supports (Collaboration) 2024/01
2.	Papers	Oxygenase mimicking immobilised iron complex catalysts for alkane hydroxylation with H₂O₂ (Collaboration) 2023/07
3.	Papers	Thermosalient effect of naphthalene diimide and tetrachlorocobaltate hybrid and changes of color and magnetic property by ammonia vapor (Collaboration) 2023/07
4.	Papers	Heteroleptic and Homoleptic Iron(III) Complexes with a Tris(N-Heterocyclic Carbene) Borate Ligand: Synthesis, Characterization, and Catalytic Application (Collaboration) 2023/03
5.	Papers	Selective alkane hydroxylation and alkene epoxidation using H2O2 and Fe(II) catalysts electrostatically attached to a fluorinated surface (Collaboration) 2023/02
6.	Papers	The Conversion of Superoxide to Hydroperoxide on Cobalt(III) Depends on the Structural and Electronic Properties of Azole-Based Chelating Ligands (Collaboration) 2022/09
7.	Papers	Aliphatic C-H hydroxylation activity and durability of a nickel complex catalyst according to the molecular structure of the bis(oxazoline) ligands (Collaboration) 2021/07
8.	Papers	Efficient alkane hydroxylation catalysis of nickel(II) complexes with oxazoline donor containing tripodal tetradentate ligands (Collaboration) 2020/04
9.	Papers	Heteroleptic cobalt(III) acetylacetonato complexes with N-heterocyclic carbine-donating scorpionate ligands: synthesis, structural characterization and catalysis (Collaboration) 2019/02
10.	Papers	A monomeric manganese(II) catecholato complex: Synthesis, crystal structure, and reactivity toward molecular oxygen (Collaboration) 2019/01
11.	Papers	Tuning the O₂ Binding Affinity of Cobalt(II) Centers by Changing the Structural and Electronic Properties of the Distal Substituents on Azole-Based Chelating Ligands (Collaboration) 2018/11
12.	Papers	Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate To^M to Control the Structural Properties and Reactivities of Cobalt Centers (Collaboration) 2018/06
13.	Papers	Alkane Oxidation Reactivity of Heterogeneous Metal Complex Catalysts with Silica-immobilized (2-pyridylmethyl)amine Type Ligands (Collaboration) 2017/12
14.	Papers	Immobilization of a Boron Center-functionalized Scorpionate Ligand on Mesoporous Silica Supports for Heterogeneous Tp-based Catalysts (Collaboration) 2017/03
15.	Papers	Formation of Ru Active Species by Ion-exchange Method for Aqueous Phase Reforming of Acetic Acid (Collaboration) 2016/11
16.	Papers	A pseudotetrahedral nickel(II) complex with a tridentate oxazoline-based scorpionate ligand: chlorido[tris(4,4-dimethyloxazolin-2-yl)- phenylborato]nickel(II) (Collaboration) 2016/11
17.	Papers	Synthesis, Characterization and Aerobic Alcohol Oxidation Catalysis of Palladium(II) Complexes with a Bis(imidazolyl)borate ligand (Collaboration) 2016/06
18.	Papers	Characterization of Mononuclear Non-heme Iron(III)-SuperoxoComplex with a Five-Azole Ligand Set (Collaboration) 2015/05
19.	Papers	Effects of Re addition upon aqueous phase reforming of ethanol over TiO2 supported Rh and Ir catalysts (Collaboration) 2015/03
20.	Papers	Mimicking the Active Sites of Non-heme Iron Oxygenases on the Solid Supports of Catalysts:Formation of Immobilized Iron Complexes with Imidazolyl and Carboxylate Ligands (Collaboration) 2015/02
21.	Papers	Structural Characterization and Oxidation Reactivity of a Nickel(II) Acylperoxo Complex (Collaboration) 2013/04
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■ Academic conference presentation

1.	2018/08/08	Oxidation catalysis of Au nano-particles immobilized on thiol-functionalized mesoporous silicate supports (The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8))
2.	2018/08/01	Oxygen activation ability of mononuclear cobalt(II) complexes with N5 donor sets and their reactivity (43rd International Conference on Coordination Chemistry)
3.	2018/08/01	Catalytic alkane oxidation activity of late 3d transition metal complexes with tris(oxazolinylmethyl)amine ligand (43rd International Conference on Coordination Chemistry)
4.	2018/08/01	Non-heme iron complexes with bis(imidazolyl)borate ligands for mimicking biological O2-activating iron sites, 43rd International Conference on Coordination Chemistry (43rd International Conference on Coordination Chemistry)
5.	2018/08/01	Alkane Oxidation by Homogeneous and Immobilized Ni(II) Complex Catalysts with BOX-type Ligands (43rd International Conference on Coordination Chemistry)
6.	2018/06/01	Design of Immobilized Metallocomplex Catalysts as Bio-inspired Catalysts for Selective Hydrocarbon Oxidation (Korea-Taiwan-Japan Bioinorganic Chemistry Symposium 2018)
7.	2016/09/29	Dioxygen Activation on Mononuclear Non-heme Iron and Cobalt Complexes (Japan-Korea-Taiwan Bioinorganic Chemistry Symposium 2016)
8.	2015/12/16	Effect of Sn addition on the conversion reaction of ethanol to the C4 compounds over Ru/Al2O3 catalyst (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
9.	2015/12/16	Effect of Sn addition on the conversion reaction of ethanol to the C4 compounds over Ru/Al2O3 catalyst (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
10.	2015/12/16	Preparation and catalytic oxidation properties of Au nanoparticles catalysts immobilized on thiol functionalized mesoporous materials (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
11.	2015/12/16	Alkane Oxygenation Catalysis of Nickel Complexes with Oxazoline-based Bidentate and Tridentate Ligands (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
12.	2015/12/16	Development of multi-functionalized poly(oxazolinyl)borate ligands and characterization of their nickel(II) complexes (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
13.	2015/12/16	Development of homogeneous and heterogeneous nickel complex catalysts based on triazolyl-BOX ligands and their catalytic activities toward alkane oxidation with mCPBA (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
14.	2015/12/16	Reactivity of Nickel-Acylperoxo Complexes (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
15.	2015/12/16	Characterization of mononuclear non-heme cobalt(III) dioxygen complexes with N5 donor sets (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
16.	2015/12/16	Characterization of mononuclear nonheme iron(III) superoxo and hydroperoxo complexes with N5 donor set (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
17.	2015/12/16	Construction of non-heme iron oxygenases-mimicking active sites on mesoporous silica supports (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
18.	2015/12/16	Aerobic alkane oxidation catalysis of iron and cobalt complexes with scorpionate ligands (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
19.	2013/08/05	Reactivity Control of Immobilized Metal Complex Catalysts by the Ligand Site Density on Material Surface (The 16th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis)
20.	2013/08/05	Bio-inspired Immobilized Metallocomplex Catalysts with Imidazolyl Group Containing Ligands Mimicking Active Sites of Non-heme Metalloenzymes (The 16th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis)
21.	2014/07/14	Catalytic Alkane Hydroxylation by Nickel Complexes with mCPBA (XXVI International Conference on Organometallic Chemistry)
22.	2014/07/21	Alkane Oxidation by Immobilized Metal Complex Catalysts: Effect of Surface Density of Ligands (41th International Conference on Coordination Chemistry)
23.	2014/07/21	CATALYTIC ALKANE HYDROXYLATION BY NICKEL COMPLEXES THROUGH PEROXIDES ACTIVATION (41st International Conference on Coordination Chemistry)
24.	2018/08/08	Oxidation catalysis of Au nano-particles immobilized on thiol-functionalized mesoporous silicate supports (The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8))
25.	2018/08/01	Oxygen activation ability of mononuclear cobalt(II) complexes with N5 donor sets and their reactivity (43rd International Conference on Coordination Chemistry)
26.	2018/08/01	Catalytic alkane oxidation activity of late 3d transition metal complexes with tris(oxazolinylmethyl)amine ligand (43rd International Conference on Coordination Chemistry)
27.	2018/08/01	Non-heme iron complexes with bis(imidazolyl)borate ligands for mimicking biological O2-activating iron sites, 43rd International Conference on Coordination Chemistry (43rd International Conference on Coordination Chemistry)
28.	2018/08/01	Alkane Oxidation by Homogeneous and Immobilized Ni(II) Complex Catalysts with BOX-type Ligands (43rd International Conference on Coordination Chemistry)
29.	2018/06/01	Design of Immobilized Metallocomplex Catalysts as Bio-inspired Catalysts for Selective Hydrocarbon Oxidation (Korea-Taiwan-Japan Bioinorganic Chemistry Symposium 2018)
30.	2016/09/29	Dioxygen Activation on Mononuclear Non-heme Iron and Cobalt Complexes (Japan-Korea-Taiwan Bioinorganic Chemistry Symposium 2016)
31.	2015/12/16	Effect of Sn addition on the conversion reaction of ethanol to the C4 compounds over Ru/Al2O3 catalyst (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
32.	2015/12/16	Effect of Sn addition on the conversion reaction of ethanol to the C4 compounds over Ru/Al2O3 catalyst (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
33.	2015/12/16	Preparation and catalytic oxidation properties of Au nanoparticles catalysts immobilized on thiol functionalized mesoporous materials (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
34.	2015/12/16	Alkane Oxygenation Catalysis of Nickel Complexes with Oxazoline-based Bidentate and Tridentate Ligands (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
35.	2015/12/16	Development of multi-functionalized poly(oxazolinyl)borate ligands and characterization of their nickel(II) complexes (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
36.	2015/12/16	Development of homogeneous and heterogeneous nickel complex catalysts based on triazolyl-BOX ligands and their catalytic activities toward alkane oxidation with mCPBA (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
37.	2015/12/16	Reactivity of Nickel-Acylperoxo Complexes (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
38.	2015/12/16	Characterization of mononuclear non-heme cobalt(III) dioxygen complexes with N5 donor sets (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
39.	2015/12/16	Characterization of mononuclear nonheme iron(III) superoxo and hydroperoxo complexes with N5 donor set (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
40.	2015/12/16	Construction of non-heme iron oxygenases-mimicking active sites on mesoporous silica supports (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
41.	2015/12/16	Aerobic alkane oxidation catalysis of iron and cobalt complexes with scorpionate ligands (The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015))
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■ Belonging society

1.	1999/06～	Catalysis Society of Japan
2.	1999/01～	American Chemical Society
3.	1990/01～	Chemical Society of Japan

■ Research topic, funded research, and department laboratory expense

1.	2016/10～2023/03	Development of organic-inorganic hybrid catalysts for methane oxidation
2.	2006/04～	Development of biomimetic oxidation catalysts

■ Home Page

http://apchem2.kanagawa-u.ac.jp/hikichilab/sub5.html

■ Research Field

2001/03

Progress Award for Young Chemist, Chemical Society of Japan

■ Department laboratory expense researcher number

10282857